First-Principles Calculations to Investigate the Third-Order Elastic Constants and Mechanical Properties of Mg, Be, Ti, Zn, Zr, and Cd

We present theoretical studies for the third-order elastic constants of Mg, Be, Ti, Zn, Zr, and Cd with a hexagonal-close-packed (HCP) structure. ,e method of homogeneous deformation combined with first-principles total-energy calculations is employed. ,e deformation gradient Fij is applied to the crystal lattice vectors ri, and the elastic strain energy can be obtained from the firstprinciples calculation. ,e second- and third-order elastic constants are extracted by a polynomial fit to the calculated energystrain results. In order to assure the accuracy of our method, we calculated the complete set of the equilibrium lattice parameters and second-order elastic constants for Mg, Be, Ti, Zn, Zr, and Cd, and our results provide better agreement with the previous calculated and experimental values. Besides, we have calculated the pressure derivatives of SOECs related to third-order elastic constants, and high-pressure effects on elastic anisotropy, ductile-to-brittle criterion, and Vickers hardness are also investigated. ,e results show that the hardness model Hv = 1.877(k2G) 0.585 is more appropriate than Hv = 2(k2G) 0.585 − 3 for HCP metals under high pressure.