Fang, Qingqing and Xu, Yan and Yan, Xiaosheng and Jiang, Tao and Jiang, Yunbao (2022) Synthetic approaches to metal-coordination-directed macrocyclic complexes. Frontiers in Chemistry, 10. ISSN 2296-2646
pubmed-zip/versions/1/package-entries/fchem-10-1078432/fchem-10-1078432.pdf - Published Version
Download (1MB)
Abstract
Metal-coordination-directed macrocyclic complexes, in which macrocyclic architectures are formed by metal-ligand coordination interactions, have emerged as attractive supramolecular scaffolds for the creation of materials for applications in biosensing and therapeutics. Despite recent progress, uncontrolled multicyclic cages and linear oligomers/polymers is the most likely outcome from metal-ligands assembly, representing a challenge to current synthetic methods. Herein we outlined the state-of-art synthetic approaches to the metal-coordination-directed macrocyclic complexes by using foldable ligands or through assembly of amphiphilic ligands. This mini-review offers a guideline for the efficient preparation of metal-coordination-directed macrocyclic complexes with predictable and controllable structures, which may find applications in many biology-related areas.
Item Type: | Article |
---|---|
Subjects: | STM Library > Chemical Science |
Depositing User: | Managing Editor |
Date Deposited: | 23 Jan 2023 06:28 |
Last Modified: | 15 May 2024 09:32 |
URI: | http://open.journal4submit.com/id/eprint/952 |